Rational design of semiconductor metal oxide nanomaterials for gas sensing by template-assisted synthesis: a survey

Yuanyang XUN; Siqi LI; Feiyu ZHANG; Yan HONG; Ke XU; Ligang CHEN; Song LIU; Bin LI

doi:10.1631/FITEE.2200552

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Rational design of semiconductor metal oxide nanomaterials for gas sensing by template-assisted synthesis: a survey

Regular Papers | Updated：2023-07-24

- Rational design of semiconductor metal oxide nanomaterials for gas sensing by template-assisted synthesis: a survey
- 模板辅助合成半导体金属氧化物气敏纳米材料的合理设计：综述
- Frontiers of Information Technology & Electronic Engineering Vol. 24, Issue 7, Pages: 945-963(2023)
- Affiliations：
  
  MOE Key Laboratory of Forest Plant Ecology, College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China
- Author bio：
  
  ‡Corresponding author
  carlosliusong@nefu.edu.cn
  libinzh62@163.com
- Funds：
- DOI：10.1631/FITEE.2200552
  CLC： X831; TP212
- Received：08 November 2022，
  
  Revised：2023-02-22，
  
  Published：0 July 2023
- Accepted：
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Yuanyang XUN, Siqi LI, Feiyu ZHANG, et al. Rational design of semiconductor metal oxide nanomaterials for gas sensing by template-assisted synthesis: a survey[J]. Frontiers of Information Technology & Electronic Engineering, 2023, 24(7): 945-963.
DOI：

Yuanyang XUN, Siqi LI, Feiyu ZHANG, et al. Rational design of semiconductor metal oxide nanomaterials for gas sensing by template-assisted synthesis: a survey[J]. Frontiers of Information Technology & Electronic Engineering, 2023, 24(7): 945-963. DOI： 10.1631/FITEE.2200552.

摘要

由于城市化和工业化的快速建设所带来的气体污染，气体传感器受到广泛关注。基于半导体金属氧化物（SMO）的气体传感器具有响应高、重复性好、稳定性好、性价比高等优点，已成为气体传感器领域极其重要的元器件。通常，具有规则结构和可控形态的材料表现出更稳定且可重复的性能。然而，由于微观世界的不可控性，在材料合成过程中纳米材料往往表现出不规则、不均匀等缺点。因此，具有规整结构的一维（1D）结构、二维（2D）结构和三维（3D）结构的气敏材料的合成受到广泛关注。为了定向获得具有理想形貌和尺寸的结构规整的纳米材料，低成本且操作简洁可控的模板辅助合成法是一种非常有效的策略。本文介绍了一维、二维和三维结构的SMO传感器的形貌和性能，讨论了各种形貌对气体传感器性能（响应和稳定性）的影响，为结构稳定、性能优异的气敏材料的合成提供了新的思路。

Abstract

Gas sensors have received extensive attention because of the gas pollution caused by rapid construction of urbanization and industrialization. Gas sensors based on semiconductor metal oxide (SMO) have the advantages of high response

excellent repeatability

stability

and cost-effectiveness

and have become extremely important components in the gas sensor field. Materials with regular structures and controllable morphology exhibit more consistent and repeatable performance. However

during the process of material synthesis

because of the uncontrollability of the microcosm

nanomaterials often show irregularities

unevenness

and other shortcomings. Thus

the synthesis of gas sensors with well-aligned one-dimensional (1D) structures

two-dimensional (2D) layered structures

and three-dimensional (3D) hierarchical structures has received extensive attention. To obtain regular structured nanomaterials with desired morphologies and dimensions

a template-assisted synthesis method with low cost and controllable process seems a very efficient strategy. In this review

we introduce the morphology and performance of SMO sensors with 1D

and 3D structures

discuss the impact of a variety of morphologies on gas sensor performance (response and stability)

and shed new light on the synthesis of gas sensing materials with stable structure and excellent performance.

关键词

Keywords

references

Baek DH , Choi J , Kim J , 2019 . Fabrication of suspended nanowires for highly sensitive gas sensing . Sens Actuat B Chem , 284 : 362 - 368 . https://doi.org/10.1016/j.snb.2018.12.159 https://doi.org/10.1016/j.snb.2018.12.159

Bulemo PM , Cho HJ , Kim DH , et al. , 2018 . Facile synthesis of Pt-functionalized meso/macroporous SnO 2 hollow spheres through in situ templating with SiO 2 for H 2 S sensors . ACS Appl Mater Interfaces , 10 ( 21 ): 18183 - 18191 . https://doi.org/10.1021/acsami.8b00901 https://doi.org/10.1021/acsami.8b00901

Chen J , Feng DL , Wang C , et al. , 2020 . Gas sensor detecting 3-hydroxy-2-butanone biomarkers: boosted response via decorating Pd nanoparticles onto the {010} facets of BiVO 4 decahedrons . ACS Sens , 5 ( 8 ): 2620 - 2627 . https://doi.org/10.1021/acssensors.0c01149 https://doi.org/10.1021/acssensors.0c01149

Cheng PF , Lv L , Wang YL , et al. , 2021 . SnO 2 /ZnSnO 3 double-shelled hollow microspheres based high-performance acetone gas sensor . Sens Actuat B Chem , 332 : 129212 . https://doi.org/10.1016/j.snb.2020.129212 https://doi.org/10.1016/j.snb.2020.129212

Escobedo P , Fernández-Ramos MD , López-Ruiz N , et al. , 2022 . Smart facemask for wireless CO 2 monitoring . Nat Commun , 13 ( 1 ): 72 . https://doi.org/10.1038/s41467-021-27733-3 https://doi.org/10.1038/s41467-021-27733-3

Fei HF , Long YD , Yu HJ , et al. , 2020 . Bimodal mesoporous carbon spheres with small and ultra-large pores fabricated using amphiphilic brush block copolymer micelle templates . ACS Appl Mater Interfaces , 12 ( 51 ): 57322 - 57329 . https://doi.org/10.1021/acsami.0c16566 https://doi.org/10.1021/acsami.0c16566

Gao ZM , Wang TQ , Li XF , et al. , 2020 . Pd-decorated PdO hollow shells: a H 2 -sensing system in which catalyst nanoparticle and semiconductor support are interconvertible . ACS Appl Mater Interfaces , 12 ( 38 ): 42971 - 42981 . https://doi.org/10.1021/acsami.0c13137 https://doi.org/10.1021/acsami.0c13137

Giampiccolo A , Tobaldi DM , Leonardi SG , et al. , 2019 . Sol gel graphene/TiO 2 nanoparticles for the photocatalytic-assisted sensing and abatement of NO 2 . Appl Catal B Environ , 243 : 183 - 194 . https://doi.org/10.1016/j.apcatb.2018.10.032 https://doi.org/10.1016/j.apcatb.2018.10.032

Guo LL , Zhang B , Yang XL , et al. , 2021 . Sensing platform of PdO-ZnO-In 2 O 3 nanofibers using MOF templated catalysts for triethylamine detection . Sens Actuat B Chem , 343 : 130126 . https://doi.org/10.1016/j.snb.2021.130126 https://doi.org/10.1016/j.snb.2021.130126

Hong SH , Song N , Jiang EH , et al. , 2022 . Nickel supported on nitrogen-doped biomass carbon fiber fabricated via in-situ template technology for pH-universal electrocatalytic hydrogen evolution . J Colloid Interface Sci , 608 : 1441 - 1448 . https://doi.org/10.1016/j.jcis.2021.10.083 https://doi.org/10.1016/j.jcis.2021.10.083

Hu CH , Yu LM , Li SL , et al. , 2022 . Sacrificial template triggered to synthesize hollow nanosheet-assembled Co 3 O 4 microtubes for fast triethylamine detection . Sens Actuat B Chem , 355 : 131246 . https://doi.org/10.1016/j.snb.2021.131246 https://doi.org/10.1016/j.snb.2021.131246

Huang R , Zhu AM , Gong Y , et al. , 2013 . Facile method to prepare monodispersed hollow PtAu sphere with TiO 2 colloidal sphere as a template . Ind Eng Chem Res , 52 ( 22 ): 7432 - 7438 . https://doi.org/10.1021/ie400573c https://doi.org/10.1021/ie400573c

Hung PS , Chou YS , Huang BH , et al. , 2020 . A vertically integrated ZnO-based hydrogen sensor with hierarchical bi-layered inverse opals . Sens Actuat B Chem , 325 : 128779 . https://doi.org/10.1016/j.snb.2020.128779 https://doi.org/10.1016/j.snb.2020.128779

Ivanova A , Frka-Petesic B , Paul A , et al. , 2020 . Cellulose nanocrystal-templated tin dioxide thin films for gas sensing . ACS Appl Mater Interfaces , 12 ( 11 ): 12639 - 12647 . https://doi.org/10.1021/acsami.9b11891 https://doi.org/10.1021/acsami.9b11891

Jang JS , Koo WT , Choi SJ , et al. , 2017 . Metal organic framework-templated chemiresistor: sensing type transition from P-to-N using hollow metal oxide polyhedron via galvanic replacement . J Am Chem Soc , 139 ( 34 ): 11868 - 11876 . https://doi.org/10.1021/jacs.7b05246 https://doi.org/10.1021/jacs.7b05246

Jo YK , Jeong SY , Moon YK , et al. , 2021 . Exclusive and ultrasensitive detection of formaldehyde at room temperature using a flexible and monolithic chemiresistive sensor . Nat Commun , 12 ( 1 ): 4955 . https://doi.org/10.1038/s41467-021-25290-3 https://doi.org/10.1038/s41467-021-25290-3

Kim DH , Kim SJ , Shin H , et al. , 2019 . High-resolution, fast, and shape-conformable hydrogen sensor platform: polymer nanofiber yarn coupled with nanograined Pd@Pt . ACS Nano , 13 ( 5 ): 6071 - 6082 . https://doi.org/10.1021/acsnano.9b02481 https://doi.org/10.1021/acsnano.9b02481

Kim DH , Cha JH , Lim JY , et al. , 2020 . Colorimetric dye-loaded nanofiber yarn: eye-readable and weavable gas sensing platform . ACS Nano , 14 ( 12 ): 16907 - 16918 . https://doi.org/10.1021/acsnano.0c05916 https://doi.org/10.1021/acsnano.0c05916

Kim S , Singh G , Oh M , et al. , 2021 . An analysis of a highly sensitive and selective hydrogen gas sensor based on a 3D Cu-doped SnO 2 sensing material by efficient electronic sensor interface . ACS Sens , 6 ( 11 ): 4145 - 4155 . https://doi.org/10.1021/acssensors.1c01696 https://doi.org/10.1021/acssensors.1c01696

Koo WT , Cha JH , Jung JW , et al. , 2018 . Few-layered WS 2 nanoplates confined in Co, N-doped hollow carbon nanocages: abundant WS 2 edges for highly sensitive gas sensors . Adv Funct Mater , 28 ( 36 ): 1802575 . https://doi.org/10.1002/adfm.201802575 https://doi.org/10.1002/adfm.201802575

Li C , Qiao XK , Jian J , et al. , 2019 . Ordered porous BiVO 4 based gas sensors with high selectivity and fast-response towards H 2 S . Chem Eng J , 375 : 121924 . https://doi.org/10.1016/j.cej.2019.121924 https://doi.org/10.1016/j.cej.2019.121924

Li HJ , Zhang N , Zhao XL , et al. , 2020 . Modulation of TEA and methanol gas sensing by ion-exchange based on a sacrificial template 3D diamond-shaped MOF . Sens Actuat B Chem , 315 : 128136 . https://doi.org/10.1016/j.snb.2020.128136 https://doi.org/10.1016/j.snb.2020.128136

Li L , Tan JF , Dun MH , et al. , 2017 . Porous ZnFe 2 O 4 nanorods with net-worked nanostructure for highly sensor response and fast response acetone gas sensor . Sens Actuat B Chem , 248 : 85 - 91 . https://doi.org/10.1016/j.snb.2017.03.119 https://doi.org/10.1016/j.snb.2017.03.119

Li Q , Wu JB , Huang L , et al. , 2018 . Sulfur dioxide gas-sensitive materials based on zeolitic imidazolate framework-derived carbon nanotubes . J Mater Chem A , 6 ( 25 ): 12115 - 12124 . https://doi.org/10.1039/c8ta02036a https://doi.org/10.1039/c8ta02036a

Li RF , Qi H , Ma Y , et al. , 2020 . A flexible and physically transient electrochemical sensor for real-time wireless nitric oxide monitoring . Nat Commun , 11 ( 1 ): 3207 . https://doi.org/10.1038/s41467-020-17008-8 https://doi.org/10.1038/s41467-020-17008-8

Li Z , Zhang Y , Zhang H , et al. , 2020 . Superior NO 2 sensing of MOF-derived indium-doped ZnO porous hollow cages . ACS Appl Mater Interfaces , 12 ( 33 ): 37489 - 37498 . https://doi.org/10.1021/acsami.0c10420 https://doi.org/10.1021/acsami.0c10420

Li Z , Zhang Y , Zhang H , et al. , 2021 . MOF-derived Au-loaded Co 3 O 4 porous hollow nanocages for acetone detection . Sens Actuat B Chem , 344 : 130182 . https://doi.org/10.1016/j.snb.2021.130182 https://doi.org/10.1016/j.snb.2021.130182

Liang ZB , Qu C , Zhou WY , et al. , 2019 . Synergistic effect of Co-Ni hybrid phosphide nanocages for ultrahigh capacity fast energy storage . Adv Sci , 6 ( 8 ): 1802005 . https://doi.org/10.1002/advs.201802005 https://doi.org/10.1002/advs.201802005

Lin LS , Yang XY , Zhou ZJ , et al. , 2017 . Yolk-shell nanostructure: an ideal architecture to achieve harmonious integration of magnetic-plasmonic hybrid theranostic platform . Adv Mater , 29 ( 21 ): 1606681 . https://doi.org/10.1002/adma.201606681 https://doi.org/10.1002/adma.201606681

Liu W , Xu L , Sheng K , et al. , 2018 . A highly sensitive and moisture-resistant gas sensor for diabetes diagnosis with Pt@In 2 O 3 nanowires and a molecular sieve for protection . NPG Asia Mater , 10 ( 4 ): 293 - 308 . https://doi.org/10.1038/s41427-018-0029-2 https://doi.org/10.1038/s41427-018-0029-2

Liu WX , Sun JB , Li YN , et al. , 2023 . Low-temperature and high-selectivity butanone sensor based on porous Fe 2 O 3 nanosheets synthesized by phoenix tree leaf template . Sens Actuat B Chem , 377 : 133054 . https://doi.org/10.1016/j.snb.2022.133054 https://doi.org/10.1016/j.snb.2022.133054

Liu XJ , Duan XP , Zhang C , et al. , 2022 . Improvement toluene detection of gas sensors based on flower-like porous indium oxide nanosheets . J Alloys Compd , 897 : 163222 . https://doi.org/10.1016/j.jallcom.2021.163222 https://doi.org/10.1016/j.jallcom.2021.163222

Lu JJ , Liu DP , Zhou JC , et al. , 2017 . Porous organic field-effect transistors for enhanced chemical sensing performances . Adv Funct Mater , 27 ( 20 ): 1700018 . https://doi.org/10.1002/adfm.201700018 https://doi.org/10.1002/adfm.201700018

Luong HM , Pham MT , Guin T , et al. , 2021 . Sub-second and ppm-level optical sensing of hydrogen using templated control of nano-hydride geometry and composition . Nat Commun , 12 ( 1 ): 2414 . https://doi.org/10.1038/s41467-021-22697-w https://doi.org/10.1038/s41467-021-22697-w

Lv L , Cheng PF , Wang YL , et al. , 2020 . Sb-doped three-dimensional ZnFe 2 O 4 macroporous spheres for N-butanol chemiresistive gas sensors . Sens Actuat B Chem , 320 : 128384 . https://doi.org/10.1016/j.snb.2020.128384 https://doi.org/10.1016/j.snb.2020.128384

Ma JW , Fan HQ , Zhang WM , et al. , 2020 . High sensitivity and ultra-low detection limit of chlorine gas sensor based on In 2 O 3 nanosheets by a simple template method . Sens Actuat B Chem , 305 : 127456 . https://doi.org/10.1016/j.snb.2019.127456 https://doi.org/10.1016/j.snb.2019.127456

Masoumi S , Shokrani M , Aghili S , et al. , 2019 . Zinc oxide-based direct thermoelectric gas sensor for the detection of volatile organic compounds in air . Sens Actuat B Chem , 294 : 245 - 252 . https://doi.org/10.1016/j.snb.2019.05.063 https://doi.org/10.1016/j.snb.2019.05.063

Na HB , Zhang XF , Zhang M , et al. , 2019a . A fast response/recovery ppb-level H 2 S gas sensor based on porous CuO/ZnO heterostructural tubule via confined effect of absorbent cotton . Sens Actuat B Chem , 297 : 126816 . https://doi.org/10.1016/j.snb.2019.126816 https://doi.org/10.1016/j.snb.2019.126816

Na HB , Zhang XF , Deng ZP , et al. , 2019b . Large-scale synthesis of hierarchically porous ZnO hollow tubule for fast response to ppb-level H 2 S gas . ACS Appl Mater Interfaces , 11 ( 12 ): 11627 - 11635 . https://doi.org/10.1021/acsami.9b00173 https://doi.org/10.1021/acsami.9b00173

Nasir ME , Dickson W , Wurtz GA , et al. , 2014 . Hydrogen detected by the naked eye: optical hydrogen gas sensors based on core/shell plasmonic nanorod metamaterials . Adv Mater , 26 ( 21 ): 3532 - 3537 . https://doi.org/10.1002/adma.201305958 https://doi.org/10.1002/adma.201305958

Ogbeide O , Bae G , Yu WB , et al. , 2022 . Inkjet‐printed rGO/binary metal oxide sensor for predictive gas sensing in a mixed environment . Adv Funct Mater , 32 ( 25 ): 2113348 . https://doi.org/10.1002/adfm.202113348 https://doi.org/10.1002/adfm.202113348

Park SW , Jeong SY , Yoon JW , et al. , 2020 . General strategy for designing highly selective gas-sensing nanoreactors: morphological control of SnO 2 hollow spheres and configurational tuning of Au catalysts . ACS Appl Mater Interfaces , 12 ( 46 ): 51607 - 51615 . https://doi.org/10.1021/acsami.0c13760 https://doi.org/10.1021/acsami.0c13760

Sabri YM , Kandjani AE , Rashid SSAAH , et al. , 2018 . Soot template TiO 2 fractals as a photoactive gas sensor for acetone detection . Sens Actuat B Chem , 275 : 215 - 222 . https://doi.org/10.1016/j.snb.2018.08.059 https://doi.org/10.1016/j.snb.2018.08.059

Sanger A , Kang SB , Jeong MH , et al. , 2018 . Morphology-controlled aluminum-doped zinc oxide nanofibers for highly sensitive NO 2 sensors with full recovery at room temperature . Adv Sci , 5 ( 9 ): 1800816 . https://doi.org/10.1002/advs.201800816 https://doi.org/10.1002/advs.201800816

Seo MH , Kang K , Yoo JY , et al. , 2020 . Chemo-mechanically operating palladium-polymer nanograting film for a self-powered H 2 gas sensor . ACS Nano , 14 ( 12 ): 16813 - 16822 . https://doi.org/10.1021/acsnano.0c05476 https://doi.org/10.1021/acsnano.0c05476

Sharma B , Sharma A , Myung JH , 2021 . Selective ppb-level NO 2 gas sensor based on SnO 2 -boron nitride nanotubes . Sens Actuat B Chem , 331 : 129464 https://doi.org/10.1016/j.snb.2021.129464 https://doi.org/10.1016/j.snb.2021.129464

Shin H , Lee WJ , 2016 . Multi-shelled MgCo 2 O 4 hollow microspheres as anodes for lithium ion batteries . J Mater Chem A , 4 ( 31 ): 12263 - 12272 . https://doi.org/10.1039/c6ta03959f https://doi.org/10.1039/c6ta03959f

Shin H , Kim DH , Jung W , et al. , 2021 . Surface activity-tuned metal oxide chemiresistor: toward direct and quantitative halitosis diagnosis . ACS Nano , 15 ( 9 ): 14207 - 14217 . https://doi.org/10.1021/acsnano.1c01350 https://doi.org/10.1021/acsnano.1c01350

Sun ZQ , Liao T , Dou YH , et al. , 2014 . Generalized self-assembly of scalable two-dimensional transition metal oxide nano‑sheets . Nat Commun , 5 : 3813 . https://doi.org/10.1038/ncomms4813 https://doi.org/10.1038/ncomms4813

Tammanoon N , Iwamoto T , Ueda T , et al. , 2020 . Synergistic effects of PdO x -CuO x loadings on methyl mercaptan sensing of porous WO 3 microspheres prepared by ultrasonic spray pyrolysis . ACS Appl Mater Interfaces , 12 ( 37 ): 41728 - 41739 . https://doi.org/10.1021/acsami.0c10462 https://doi.org/10.1021/acsami.0c10462

Tan CL , Zhang H , 2015 . Wet-chemical synthesis and applications of non-layer structured two-dimensional nanomaterials . Nat Commun , 6 : 7873 . https://doi.org/10.1038/ncomms8873 https://doi.org/10.1038/ncomms8873

Teng Y , Zhang XF , Xu TT , et al. , 2020 . A spendable gas sensor with higher sensitivity and lowest detection limit towards H 2 S: porous α‍-Fe 2 O 3 hierarchical tubule derived from poplar branch . Chem Eng J , 392 : 123679 . https://doi.org/10.1016/j.cej.2019.123679 https://doi.org/10.1016/j.cej.2019.123679

Tie Y , Ma SY , Pei ST , et al. , 2020 . Pr doped BiFeO 3 hollow nanofibers via electrospinning method as a formaldehyde sensor . Sens Actuat B Chem , 308 : 127689 . https://doi.org/10.1016/j.snb.2020.127689 https://doi.org/10.1016/j.snb.2020.127689

Wang H , Luo YY , Li K , et al. , 2022 . Porous α-Fe 2 O 3 gas sensor with instantaneous attenuated response toward triethylamine and its reaction kinetics . Chem Eng J , 427 : 131631 . https://doi.org/10.1016/j.cej.2021.131631 https://doi.org/10.1016/j.cej.2021.131631

Wang L , Sun LY , Bian FK , et al. , 2022 . Self-bonded hydrogel inverse opal particles as sprayed flexible patch for wound healing . ACS Nano , 16 ( 2 ): 2640 - 2650 . https://doi.org/10.1021/acsnano.1c09388 https://doi.org/10.1021/acsnano.1c09388

Wang Q , Wu HC , Wang YR , et al. , 2021 . Ex-situ XPS analysis of yolk-shell Sb 2 O 3 /WO 3 for ultra-fast acetone resistive sensor . J Hazard Mater , 412 : 125175 . https://doi.org/10.1016/j.jhazmat.2021.125175 https://doi.org/10.1016/j.jhazmat.2021.125175

Wang TS , Jiang B , Yu Q , et al. , 2019 . Realizing the control of electronic energy level structure and gas-sensing selectivity over heteroatom-doped In 2 O 3 spheres with an inverse opal microstructure . ACS Appl Mater Interfaces , 11 ( 9 ): 9600 - 9611 . https://doi.org/10.1021/acsami.8b21543 https://doi.org/10.1021/acsami.8b21543

Wen ZY , Ren HB , Li DX , et al. , 2023 . A highly efficient acetone gas sensor based on 2D porous ZnFe 2 O 4 nanosheets . Sens Actuat B Chem , 379 : 133287 . https://doi.org/10.1016/j.snb.2023.133287 https://doi.org/10.1016/j.snb.2023.133287

Wu YY , Song BY , Zhang XF , et al. , 2021 . Microtubular α-Fe 2 O 3 /Fe 2 (MoO 4 ) 3 heterostructure derived from absorbent cotton for enhanced ppb-level H 2 S gas-sensing performance . J Alloys Compd , 867 : 158994 . https://doi.org/10.1016/j.jallcom.2021.158994 https://doi.org/10.1016/j.jallcom.2021.158994

Xia Y , Zhou LX , Yang J , et al. , 2020 . Highly sensitive and fast optoelectronic room-temperature NO 2 gas sensor based on ZnO nanorod-assembled macro-/mesoporous film . ACS Appl Electron Mater , 2 ( 2 ): 580 - 589 . https://doi.org/10.1021/acsaelm.9b00810 https://doi.org/10.1021/acsaelm.9b00810

Xie WH , Ren Y , Yu BJ , et al. , 2021 . Self-hybrid transition metal oxide nanosheets synthesized by a facile programmable and scalable carbonate-template method . Small , 17 ( 39 ): 2103176 . https://doi.org/10.1002/smll.202103176 https://doi.org/10.1002/smll.202103176

Xiong Y , Zhu ZY , Ding DG , et al. , 2018 . Multi-shelled ZnCo 2 O 4 yolk-shell spheres for high-performance acetone gas sensor . Appl Surf Sci , 443 : 114 - 121 . https://doi.org/10.1016/j.apsusc.2018.02.189 https://doi.org/10.1016/j.apsusc.2018.02.189

Xu SP , Sun FQ , Gu FL , et al. , 2014 . Photochemistry-based method for the fabrication of SnO 2 monolayer ordered porous films with size-tunable surface pores for direct application in resistive-type gas sensor . ACS Appl Mater Interfaces , 6 ( 2 ): 1251 - 1257 . https://doi.org/10.1021/am4050844 https://doi.org/10.1021/am4050844

Xue MQ , Li FW , Chen D , et al. , 2016 . High-oriented polypyrrole nanotubes for next-generation gas sensor . Adv Mater , 28 ( 37 ): 8265 - 8270 . https://doi.org/10.1002/adma.201602302 https://doi.org/10.1002/adma.201602302

Yang JQ , Han WJ , Ma J , et al. , 2021 . Sn doping effect on NiO hollow nanofibers based gas sensors about the humidity dependence for triethylamine detection . Sens Actuat B Chem , 340 : 129971 . https://doi.org/10.1016/j.snb.2021.129971 https://doi.org/10.1016/j.snb.2021.129971

Yang S , Sun J , Xu L , et al. , 2020 . Au@ZnO functionalized three‍-‍dimensional macroporous WO 3 : a application of selective H 2 S gas sensor for exhaled breath biomarker detection . Sens Actuat B Chem , 324 : 128725 . https://doi.org/10.1016/j.snb.2020.128725 https://doi.org/10.1016/j.snb.2020.128725

Yang XY , Shi YT , Xie KF , et al. , 2022 . Cocrystallization enabled spatial self-confinement approach to synthesize crystalline porous metal oxide nanosheets for gas sensing . Angew Chem Int Ed , 61 ( 37 ): e202207816 . https://doi.org/10.1002/anie.202207816 https://doi.org/10.1002/anie.202207816

Yao Y , Yin ML , Yan JQ , et al. , 2017 . Controllable synthesis of Ag-WO 3 core-shell nanospheres for light-enhanced gas sensors . Sens Actuat B Chem , 251 : 583 - 589 . https://doi.org/10.1016/j.snb.2017.05.007 https://doi.org/10.1016/j.snb.2017.05.007

Yi SY , Song YG , Park JY , et al. , 2019 . Morphological evolution induced through a heterojunction of W-decorated NiO nanoigloos: synergistic effect on high-performance gas sensors . ACS Appl Mater Interfaces , 11 ( 7 ): 7529 - 7538 . https://doi.org/10.1021/acsami.8b18678 https://doi.org/10.1021/acsami.8b18678

Yuan HY , Aljneibi SAAA , Yuan JR , et al. , 2019 . ZnO nanosheets abundant in oxygen vacancies derived from metal-organic frameworks for ppb-level gas sensing . Adv Mater , 31 ( 11 ): 1807161 . https://doi.org/10.1002/adma.201807161 https://doi.org/10.1002/adma.201807161

Yuan KP , Wang CY , Zhu LY , et al. , 2020 . Fabrication of a micro-electromechanical system-based acetone gas sensor using CeO 2 nanodot-decorated WO 3 nanowires . ACS Appl Mater Interfaces , 12 ( 12 ): 14095 - 14104 . https://doi.org/10.1021/acsami.9b18863 https://doi.org/10.1021/acsami.9b18863

Zeng G , Wu C , Chang Y , et al. , 2019 . Detection and discrimination of volatile organic compounds using a single film bulk acoustic wave resonator with temperature modulation as a multiparameter virtual sensor array . ACS Sens , 4 ( 6 ): 1524 - 1533 . https://doi.org/10.1021/acssensors.8b01678 https://doi.org/10.1021/acssensors.8b01678

Zeng QR , Feng JT , Lin XC , et al. , 2020 . One-step facile synthesis of a NiO/ZnO biomorphic nanocomposite using a poplar tree leaf template to generate an enhanced gas sensing platform to detect n-butanol . J Alloys Compd , 815 : 150550 . https://doi.org/10.1016/j.jallcom.2019.05.018 https://doi.org/10.1016/j.jallcom.2019.05.018

Zhang B , Sun JY , Gao PX , 2021 . Low-concentration NO x gas analysis using single bimodular ZnO nanorod sensor . ACS Sens , 6 ( 8 ): 2979 - 2987 . https://doi.org/10.1021/acssensors.1c00834 https://doi.org/10.1021/acssensors.1c00834

Zhang LH , Dong B , Xu L , et al. , 2017 . Three-dimensional ordered ZnO-Fe 3 O 4 inverse opal gas sensor toward trace concentration acetone detection . Sens Actuat B Chem , 252 : 367 - 374 . https://doi.org/10.1016/j.snb.2017.05.167 https://doi.org/10.1016/j.snb.2017.05.167

Zhang XM , Dong ZJ , Liu SR , et al. , 2017 . Maize straw-templated hierarchical porous ZnO:Ni with enhanced acetone gas sensing properties . Sens Actuat B Chem , 243 : 1224 - 1230 . https://doi.org/10.1016/j.snb.2016.12.076 https://doi.org/10.1016/j.snb.2016.12.076

Zhao C , Zhou AW , Dou YB , et al. , 2021 . Dual MOFs template-directed fabrication of hollow-structured heterojunction photocatalysts for efficient CO 2 reduction . Chem Eng J , 416 : 129155 . https://doi.org/10.1016/j.cej.2021.129155 https://doi.org/10.1016/j.cej.2021.129155

Zhao RJ , Zhang X , Peng SJ , et al. , 2020 . Shaddock peels as bio-templates synthesis of Cd-doped SnO 2 nanofibers: a high performance formaldehyde sensing material . J Alloys Compd , 813 : 152170 . https://doi.org/10.1016/j.jallcom.2019.152170 https://doi.org/10.1016/j.jallcom.2019.152170

Zheng XZ , Zhang Z , Meng SG , et al. , 2020 . Regulating charge transfer over 3D Au/ZnO hybrid inverse opal toward efficiently photocatalytic degradation of bisphenol A and photoelectrochemical water splitting . Chem Eng J , 393 : 124676 . https://doi.org/10.1016/j.cej.2020.124676 https://doi.org/10.1016/j.cej.2020.124676

Zheng YY , Wang LQ , Tian HW , et al. , 2021 . Bimetal carbonaceous templates for multi-shelled NiCo 2 O 4 hollow sphere with enhanced xylene detection . Sens Actuat B Chem , 339 : 129862 . https://doi.org/10.1016/j.snb.2021.129862 https://doi.org/10.1016/j.snb.2021.129862

Zhu XQ , Li J , Ali RN , et al. , 2018 . Toward a high-performance Li-ion battery: constructing a Co 1- x S/ZnS@C composite derived from metal-organic framework @3D disordered polystyrene sphere template . Mater Des , 160 : 636 - 641 . https://doi.org/10.1016/j.matdes.2018.10.011 https://doi.org/10.1016/j.matdes.2018.10.011

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